The R&B singer and White Stripes frontman have teamed up for "Another Way to Die," the first duet to be chosen as a Bond theme.
Producers said White has written and produced the song and also plays drums, as well as singing with 11-time Grammy winner Keys.
Previous Bond themes have been performed by the likes of Paul McCartney, Duran Duran and Madonna, and each new film's tune always produces intense speculation.
Troubled diva Amy Winehouse had previously been linked to the "Quantum of Solace" theme. But her collaborator Mark Ronson said earlier this year that work on a song for the film had been abandoned because Winehouse was not ready to record.
Other reports had suggested singers Duffy and Leona Lewis were being considered.
"Quantum of Solace" sees Daniel Craig return as suave secret agent 007. It is due for release in Britain on Oct. 31 and around the world in November.
Alicia Keys to take 5 people on trip to Africa
Dec 1, 2009 6:00 am PST
Alicia Keys says her first visit to Africa was so emotional and inspiring that she is ready to take others there to experience something similar. The Grammy-winning singer is launching a contest through her charity, Keep a Child Alive, th...
No holding back for Alicia Keys on "Freedom"
Nov 6, 2009 7:00 pm PST
An unseasonal gust of wind greets Alicia Keys as she steps out of a doorway behind a Beverly Hills hotel on a late October afternoon. Decked out in a black leather vest and black leggings brightly accented by turquoise suede knee-high boo ...
Knowles, Keys, Hudson grab music, film Image noms
Jan 7, 2009 10:00 am PST
Beyonce Knowles, Alicia Keys and Jennifer Hudson are all multitasking for the NAACP Image Awards, earning nominations Wednesday in both music and film categories. Knowles, Keys and Hudson are competing against one another for outstanding ...
Jack White, Alicia Keys hit chart with Bond theme
Nov 20, 2008 8:00 pm PST
Recording a James Bond theme is not a guarantee for chart success -- just ask Tina Turner ("Goldeneye"), a-ha ("The Living Daylights") or Sheryl Crow ("Tomorrow Never Dies"). Jack White and Alicia Keys have avoided such a fate, as their d...
Alicia Keys leads American Music Award nominees
Oct 14, 2008 12:00 pm PDT
Alicia Keys had a leading five nominations for the 2008 American Music Awards, including artist of the year and favorite female artist in both the pop/rock and soul/R&B categories. Coldplay and the Eagles had four nominations each, while ...